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CY8251 Syllabus PHYSICAL AND ORGANIC CHEMISTRY Regulation 2017 Anna University

CY8251 Syllabus PHYSICAL AND ORGANIC CHEMISTRY Regulation 2017 Anna University

CY8251 Syllabus OBJECTIVES:

  • To understand the structure and reactivity of organic compounds.
  • To study about reaction mechanisms and to study the concepts of chemical kinetics and catalysis.

CY8251 Syllabus UNIT I REACTION MECHANISMS

Free radical substitutions, Electophilic addition, Aromatic Electrophilic substitutions, Nucleophilic additions, condensation reactions, nucleophilic substitutions in aliphatic and aromatic compounds, cyclo additions, Rearrangements-Beckmann, Curtius, Hofmann, cope and oxy-cope, Fries
rearrangement reactions.

CY8251 Syllabus UNIT II HETROCYCLIC COMPOUNDS IN POLYMER TECHNOLOGY

Amines, heterocyclic compounds – furan, thiophene, pyrrole, pyridine, quinoline, isoquinoline, imidazoles, thiazoles preparation , properties and uses of simple monomers likeethylene, propylene, isobutylene, butadiene, styrene, methyl methacrylate , diisocyanates, glycols, polyols, epichlorohydrin,
fluoro alkenes, acrylonitrile, vinyl chloride, vinyl acetate.

CY8251 Syllabus UNIT III STRUCTURE AND REACTIVITY IN ORGANIC COMPOUNDS

Bonding in Organic Compounds- Structure-property relationships – Electronic effects like inductive, mesomeric, electromeric and hyper conjugation effects – Free radicals, carbocations, carbanions, elementary ideas about stereo chemistry RS-nomenclature and EZ- nomenclature- conformational
isomers.

CY8251 Syllabus UNIT IV PHASE RULE

Phase rule – statements and explanation of the terms involved – condensed phase rule – construction of phase diagram – water system – sulphur system – phase rule for two component alloy systemsthermal analysis – eutectic system – Lead-Silver system – solid solutions – Phase rule for miscible, partially miscible and immiscible liquids.

CY8251 Syllabi UNIT V ELECTRO CHEMISTRY AND CORROSION

Electro Chemistry – Electrochemical series – Transport numbers and ionic mobility – Redox reaction – Galvanic cells – Electrolysis –Corrosion – chemical and electrochemical corrosions- mechanism of electrochemical and galvanic corrosions- concentration cell corrosion and microbiological corrosions –
measurement of corrosion rate.

TOTAL: 45 PERIODS

CY8251 Syllabus OUTCOME:

Obtain knowledge in structure and reactivity of organic compounds.
Familiarize the reaction mechanism and chemical kinetics.

CY8251 Syllabi REFERENCES

1. Finar I.L., “Textbook of Organic Chemistry”. ELBS,1996.

2. Glasstone, S., and D. Lewis. “Elements of Physical Chemistry”. Macmillan, 1995.

3. Maron and C.F. Pruton “Physical Chemistry” Macmillan, 1990.

4. Morrison and Boyd, “Organic Chemistry”. Prentice Hall,1992.

 

Subject Name PHYSICAL AND ORGANIC CHEMISTRY
Subject Code CY8251
Regulation 2017
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Semester 2 Anna University Regulation 2017 Syllabus.

Syllabus for sem 2 Anna University Regulation 2017.

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